石墨烯基柔性复合材料应用于超级电容器的研究进展
超级电容器由于具有功率密度高、循环寿命长、使用温度范围宽等优点受到广泛研究。石墨烯基电极材料，凭借其卓越的物理与化学特性，在超级电容器领域展现出诱人的应用前景。然而，石墨烯在制备与应用过程中易于发生堆叠与团聚，这一现象显著削弱了其储能性能，成为制约其广泛应用的瓶颈。为克服这一难题，研究者们巧妙地将石墨烯与其他电极材料相结合，通过复合策略，成功开发出石墨烯基柔性复合电极材料。为此，这篇文章综述石墨烯在柔性超级电容器领域的最新应用进展。专门聚焦于三类复合材料体系：石墨烯/ 碳基复合材料、石墨烯/ 导电聚合物复合材料以及石墨烯/ 过渡金属化合物复合材料，总结了不同石墨烯基柔性复合材料应用于超级电容器的研究进展，仅供参考。
[1] Arico A S, Bruce P, Scrosati B, et al. Nanostructured materials for advanced energy conversion and storage devices［J］．Nature, 2005, 4: 366-377.
[2] Peng X, Peng L, Wu C Z, et al. Two dimensional nanomaterials for flexible supercapacitors［J］．Chemical Society Reviews, 2014, 43(10): 3303-3323.
[3] Dubal D P, Chodankar N R, Kim D H, et al. Towards flexible solid-state supercapacitors for smart and wearable electronics［J］．Chemical Society Reviews, 2018, 47.
[4] Huang Y, Liang J, Chen Y. An Overview of the Applications of Graphene-Based Materials in Supercapacitors［J］．Small, 2012, 8(12):1805-1834.
[5] An J, Li J P, Chen W X, et al. Electrochemical study and application on shikonin at poly (diallyldimethylammonium chloride) functionalized graphene sheets modified glass carbon electrode［J］．2013, 29(4):798-805.
[6] 李宁，陈涛．石墨烯基电极材料在柔性全固态超级电容器中的研究进展［J］．应用化学，2018.
[7] Zang X., Jiang Y., Sanghadasa M., Lin L., Chemical vapor deposition of 3D graphene/carbon nanotubes networks for hybrid supercapacitors, Sensors and Actuators A:Physical 304 (2020).
[8] Jeong H.K., Ghanashyam G., A Thermally Reduced Graphite Oxide and Carbon Nanotube Composite for Supercapacitor Applications, New Physics: Sae Mulli 68 (2018)181-184.
[9] Xu J, Wang K, Zu S Z, et al. Hierarchical Nanocomposites of Polyaniline Nanowire Arrays on Graphene Oxide Sheets with Synergistic Effect for Energy Storage［J］．Acs Nano, 2010, 4(9):5019-5026.
[10] Cai X., Sun K., Qiu Y., Jiao X., Recent Advances in Graphene and Conductive Polymer Composites for Supercapacitor Electrodes: A Review, Crystals 11 (2021).
[11] Cong H P, Ren X C, Wang P, et al. Flexible graphene-polyaniline composite paper for high-performance supercapacitor［J］．Energy & Environmental Science, 2013,6(4):1185-1191.
[12] Rui X, Tan H, Yan Q., Nanostructured metal sulfides for energy storage［J］．Nanoscale，2014，6(17): 9889-9924.
[13] Li Q., Hu X., Yang Q., Yan Z., Kang L., Lei Z., Yang Z., Liu Z., Electrocapacitive performance of graphene/Co3O4 hybrid material prepared by a nanosheet assembly route, Electrochimica Acta 119 (2014) 184-191.